The molecular weight of the copolymers was exceptionally high compared with that of normally biosynthesized P(3HB) but showed a decreasing trend with higher addition of 3M2MP precursor, which may induce a chain-transfer reaction during polymerization [ 34 ].
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Poly(3-mercapto-2-methylpropionate), a Novel α-Methylated Bio-Polythioester with Rubber-like Elasticity, and Its Copolymer with 3-hydroxybutyrate: Biosynthesis and Characterization.
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