Thermodynamics and Kinetics of Electron Transfer of Electrode-Immobilized Small Laccase from <i>Streptomyces coelicolor</i>.

The reduction thermodynamics at pH 7, compared with those for other T1 centers in laccases and cupredoxins indicate that the positive E°′ value for these centers invariably have an enthalpic origin as both enthalpic and entropic terms are negative, although the latter term may be significant, as for SLAC ( Table 2 ).

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