Continuous Square Wave Voltammetry for High Information Content Interrogation of Conformation Switching Sensors.

According to the trend given in the plot for ATP, a maximum could not be determined since the plots depict an increasing trend with 1/ f.

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When studying K 3 [Fe(CN) 6 ] with 0.1 mM KCl, with traditional square wave voltammetry, the peak current increases monotonically until ∼625 Hz followed by a decreasing trend in peak current as expected since the reaction behaves in a quasi-reversible way at these higher frequencies because of the finite electron transfer kinetics. 1 The response of ferrocene with 0.1 mM TBAPF 6 , conversely, plateaus at a similar frequency indicating the reaction behaving reversibly even at the highest frequency tested (2500 Hz).

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