The optical properties of compounds featuring n =1–5 anions show a clear trend as well as an outlier, a low band gap of 1.72 eV for [Hpyz] 4 [Sb 10 I 34 ], that can be well understood using quantum chemical investigations.
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Establishing Family Relations in Group 15 Halogenido Metalates with the Largest Molecular Antimony Iodide Anion.
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