Under these circumstances, one can use hygroscopic metal salts (often hydrated salts) with a marked trend to capture water when mixed with organic anions, in such a way that the mixture, once sealed and subject to heat, may possess enough solvent as to completely mix the reagents and promote the crystallization aided by the autogenous pressure generated in the vessel.
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A Lamellar Zn-Based Coordination Polymer Showing Increasing Photoluminescence upon Dehydration.
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