Previous studies on the reactivity of 1a indicated a marked trend of this complex to undergo cycloaddition processes at its Mo = P double bond when reacting with unsaturated organic molecules, 11 , 12 which therefore seemed an excellent candidate for inspecting its ability to activate and cleave single E–H bonds.
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E-H Bond Cleavage Processes in Reactions of Heterometallic Phosphinidene-Bridged MoRe and MoMn Complexes with Hydrogen and p-Block Element Hydrides.
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