A clear trend from over 0.7 to 0.5 in the Mark–Houwink exponent and a decrease in R g /R h from 1.7 to 1.0 point to the formation of nanogels, more rigid and less permeable than the starting coils.
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"To Be or Not to Be" of a Polymer Nanogel-Unravelling the Relationship of Product Properties vs. Synthesis Conditions Governing the Radiation Crosslinking of Poly(acrylic acid) Using GPC/SEC-MALLS.
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