At 303.15 K, the excess tends to be positive, and after that, a negative trend follows.
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Experimental and <i>in silico</i> insights: interaction of dimethyl sulphoxide with 1-hexyl-2-methyl imidazolium bromide/1-octyl-2-methyl imidazolium bromide at different temperatures.
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The sentences
But at higher temperatures, there is a positive trend at all mole fractions of [HMIM][Br].
48 With the temperature rise, the molar volume displays an increasing trend due to the mutual loss of dipolar association and the constituent molecules' differences in shape and size ( Table 3 ).