There is a clear trend in the crystal structures of solvent-free ( Me N)Li, ( iPr N)Li and ( t Bu N)Li ( Scheme 4 ).
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s-Block metal complexes of superbulky (<sup><i>t</i></sup>Bu<sub>3</sub>Si)<sub>2</sub>N<sup>-</sup>: a new weakly coordinating anion?
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