The important contribution from π-stacking interaction between parallel aromatic rings should be also encountered thus giving rise to quite significant D2a and D2b dimer interaction energies of 34.5 and 37.3 kJ mol −1 , respectively ( Table 1 ).
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Ethynyl-substituted benzosiloxaboroles: the role of C(π)⋯B interactions in their crystal packing and use in Cu(i)-catalyzed 1,3-dipolar cycloaddition.
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