Polyoxometalate Ligands Reveal Different Coordination Chemistries Among Lanthanides and Heavy Actinides.

With the two phases crystallizing, two distinct trends are observed. For the light lanthanides complexes, there is a clear trend from Ce 3+ to Eu 3+ , with a strong shortening of the distance between the PW 11 ligands from 9.182 to 8.829 Å ( Figure 5 a).

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