Thermodynamic Modulation of Dihydrogen Activation Through Rational Ligand Design in Ge^II-Ni⁰ Complexes.

Throughout the series of ligands, we see a clear trend in the MBO of the Ni–Ge bond with the partial charge of the Ge and Ni atoms, which also correlates with measured UV/vis and H 2 activation parameters (vide infra).

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