Whereas the q(IBO) of C in the parent cobalt bis(dicarbollide) ion was computed as −0.22, that of C to which N 3 is bonded amounts to 0.00, with the electron-withdrawing character of the azide group in this system being quite significant.
← all excerpts
Carbon-Substituted Amines of the Cobalt Bis(dicarbollide) Ion: Stereochemistry and Acid-Base Properties.
1
—
—