Competition between One- and Two-Electron Unimolecular Reactions of Late 3d-Metal Complexes [(Me3SiCH2)nM]-(M = Fe, Co, Ni, and Cu; n = 2-4).

Angew Chem Int Ed Engl · 2025 · PMC12087865 · PMID 40088474

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The sentences

a clear trendno p-value reported

The probed [R 4 M] − complexes show a clear trend in their unimolecular reactivity: The tendency toward a concerted reductive elimination, i.e., a two‐electron process, increases in the series M = Fe, Co, Ni, and Cu.

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Quoted from the open-access full text in Europe PMC under the licence the publisher applied. The sentence is reproduced exactly as published; the emphasis is ours.

Competition between One- and Two-Electron Unimolecular Reactions of Late 3d-Metal Complexes [(Me&lt;sub&gt;3&lt;/sub&gt;SiCH&lt;sub&gt;2&lt;/sub&gt;)&lt;sub&gt;n&lt;/sub&gt;M]&lt;sup&gt;-&lt;/sup&gt;(M = Fe, Co, Ni, and Cu; n = 2-4).

The sentences

Competition between One- and Two-Electron Unimolecular Reactions of Late 3d-Metal Complexes [(Me<sub>3</sub>SiCH<sub>2</sub>)<sub>n</sub>M]<sup>-</sup>(M = Fe, Co, Ni, and Cu; n = 2-4).