Early studies carried out in our laboratories , and elsewhere established that AuNP formation at room temperature was dependent on the aqueous dissociation equilibrium involving amino groups and the Au(III) speciation, pointing that amino groups would have to remain unprotonated to a quite significant degree with a minimum [N]/[Au] ratio required to obtain well-defined particles.
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Mild-Temperature Synthesis of Gold Colloids with Unique Features Mediated by Polymers of Biomedical Interest.
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