Overall, these data delineated a clear trend: functionalization of UiO-66, particularly with electron-donating groups such as NH 2 , drastically enhances the host–guest interaction with 8-HQ, both by promoting electronic compatibility (reduced Δ E , increased charge transfer, and dipole moments) and providing sites for specific non-covalent interactions.
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Impact of amino and methyl groups on the loading capacity of UiO-66 for 8-hydroxyquinoline: an in-depth experimental and computational analysis.
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