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First-principles investigation and photovoltaic assessment of Cs<sub>2</sub>SnZ<sub>6</sub> (Z = Cl, Br, I) lead-free perovskites for future solar technologies.

RSC Adv · 2025 · PMC12288021 · PMID 40709025

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a clear trendno p-value reported
These values reveal a clear trend of bandgap narrowing with increasing halide ionic radius, which can be attributed to the decreasing electronegativity and enhanced orbital overlap in larger halide anions.

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