Kinetic, Quantum and Thermodynamic Study of HDDMP Metal Complexes Regarding the calculated standard free energies of formation (ΔG°) for the Cu 2+ , Cd 2+ , Co 2+ and Ni 2+ complexes with the ligand in its anionic form (Equation (2)), the values show a clear trend fully consistent with the experimental extraction curves (%E vs. pH) presented in Figure 2 a,b.
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Metal-Assisted Deprotonation as a Key Step in Selective Copper Extraction: A Theoretical and Experimental Study.
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