Electric fields enhance Diels-Alderase catalysis in abyssomicin C biosynthesis.

In contrast, the averaged atom-condensed nucleophilic Fukui function f − for the atoms of the diene fragment directly involved in the Diels–Alder reaction (C10 and C13) does show a clear trend towards larger values for both carbons in poses A and B ( Fig. 2 ), i.e. , greater reactivity and nucleophilic character.

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