Scorpionate Complexes [(κn-TpPh,Me)NiS2CNR2] (n = 2, 3) as a Structural and Spectroscopic Model for Reduced Nickel-Dependent Superoxide Dismutase.

Inorg Chem · 2026 · PMC12933891 · PMID 41670496

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of marginal significanceno p-value reported

The CN bond also lengthens with increasing τ 5 value ( Table and Figure S41 ), but the range is of marginal significance, and is more strongly affected by the various N –substituents between the dithiocarbamate ligands.

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Scorpionate Complexes [(κ&lt;sup&gt;&lt;i&gt;n&lt;/i&gt;&lt;/sup&gt;-Tp&lt;sup&gt;Ph,Me&lt;/sup&gt;)NiS&lt;sub&gt;2&lt;/sub&gt;CNR&lt;sub&gt;2&lt;/sub&gt;] (&lt;i&gt;n&lt;/i&gt; = 2, 3) as a Structural and Spectroscopic Model for Reduced Nickel-Dependent Superoxide Dismutase.

The sentences

Scorpionate Complexes [(κ<sup><i>n</i></sup>-Tp<sup>Ph,Me</sup>)NiS<sub>2</sub>CNR<sub>2</sub>] (<i>n</i> = 2, 3) as a Structural and Spectroscopic Model for Reduced Nickel-Dependent Superoxide Dismutase.