While these results provide a clear trend, additional factors related to ligand functionalization should be considered, including changes in Fe Lewis acidity (influencing N 2 activation), variations in excited-state lifetime, and functionalization-induced changes in pore structure that affect reactant accessibility as well as proton transfer due to altered surface charge.
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Photocatalytic Ammonia Synthesis using Fe-Based MOFs: The Role of Ligand Functionalization.
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