The systematic investigation across alkaline-earth and alkali metal ion complexes revealed a clear trend: the stacked conformer is selectively adopted with the moderately sized divalent metal ions, the tilted conformer with the large metal ions, and the shifted conformer with the small metal ions.
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Stacked Sandwich-type Beauvericin Complex Revealed by Cryogenic Ion Mobility and Infrared Spectroscopy: Insight into Selective Transport Mechanism of Ca<sup>2+</sup> Ion.
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