In addition to the pH of the solution (redox-Bohr interactions), the reduction potential of the hemes in multiheme cytochromes can be modulated by redox interactions with neighboring hemes, which can become quite significant when iron-iron distances are very short (Fonseca et al., 2012a ).
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Rational engineering of Geobacter sulfurreducens electron transfer components: a foundation for building improved Geobacter-based bioelectrochemical technologies.
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