Both its Bi⋅⋅⋅π arene and Bi⋅⋅⋅R adducts are isoenergetic. Comparing systems in which the Bi⋅⋅⋅R motif is the most stable with systems for which the Bi⋅⋅⋅π arene motif is more stable a clear trend can be observed.
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Balancing Donor-Acceptor and Dispersion Effects in Heavy Main Group Element π Interactions: Effect of Substituents on the Pnictogen⋅⋅⋅π Arene Interaction.
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