At the An M 5 edges of dioxides, for actinides from Th to Cm, a clear trend in differences between calculated conventional XAS and HERFD is observed when the HERFD spectra are lacking some intensity on the low-incident-energy side of the main line and show the extra intensity on the high-incident-energy side, compared to conventional XAS spectral shapes.
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3d-4f Resonant Inelastic X-ray Scattering of Actinide Dioxides: Crystal-Field Multiplet Description.
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