Thus, the values for the barrier show a quite significant spread (from 13.0 to 17.6 kcal mol –1 without considering DFT results).
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Isomerization and Fragmentation Reactions on the [C<sub>2</sub>SH<sub>4</sub>] Potential Energy Surface: The Metastable Thione <i>S</i>-Methylide Isomer.
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