The orthorhombic lattice parameters follow a clear trend for 0.1 ≤ x ≤ 0.5 with .
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Oxygen Nonstoichiometry and Valence State of Manganese in La<sub>1-<i>x</i></sub> Ca <sub><i>x</i></sub> MnO<sub>3+δ</sub>.
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The orthorhombic lattice parameters follow a clear trend for 0.1 ≤ x ≤ 0.5 with .