By fitting the distribution of angle P–Li–O (P = P in PF 6 − , O = carbonyl O in EC and EMC) of CIP species with a binormal distribution, we observe a clear trend that the axial site is favored by EC, whereas EMC exhibits a higher probability for occupying the equatorial sites.
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The solvation structure, transport properties and reduction behavior of carbonate-based electrolytes of lithium-ion batteries.
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