The use of the approximated factor 1/ n should not introduce a significant error for long chains which is the case at the beginning of the pyrolysis process; nonetheless, as the pyrolysis proceeds and the chains become shorter, the error is magnified and can become quite significant.
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Thermal Pyrolysis of Polystyrene Aided by a Nitroxide End-Functionality Improved Process and Modeling of the Full Molecular Weight Distribution.
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