Tailoring the Intersystem Crossing and Triplet Dynamics of Free-Base Octaalkyl-β-oxo-Substituted Porphyrins: Competing Effects of Spin-Vibronic and NH Tautomerism Relaxation Channels.

J Phys Chem A · 2022 · PMC9059185 · PMID 35348324

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a clear trendno p-value reported

Interplay between the Spin–Vibronic Channel and NH Tautomerism As evidenced in the previous sections, we have experimentally resolved a clear trend of increasing ISC rate with an increasing number of carbonyl β-oxo substituents.

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