Structure-Activity Relationship for Di- up to Tetranuclear Macrocyclic Ruthenium Catalysts in Homogeneous Water Oxidation.

Chemistry · 2021 · PMC9290496 · PMID 33909302

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a clear trendno p-value reported

Thus, a clear trend in increasing catalytic activities with increased size of the macrocycles is evident not only per macrocycle but also per Ru unit with TOFs per Ru of 6 s −1 , 8.7 s −1 and 10.5 s −1 for the di‐, tri‐ and tetranuclear macrocycles, respectively.

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