Unbiased C3-Electrophilic Indoles: Triflic Acid Mediated C3-Regioselective Hydroarylation of N-H Indoles.

Of course, the exact nature of the (TfOH) x clusters in the biphasic TfOH/CH 2 Cl 2 mixture (or neat TfOH) is not known, but there is a clear trend in the computations supporting the idea of the formation of a 1,3‐dication stabilized by such supramolecular assemblies (Supporting Information, Figure S7).

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