Although ethylene hydrogenation is considered a structure-insensitive reaction, the TOFs of Pd/HOPG at ~ 50–100 °C show a clear trend, with the nanoparticles being about 20- to 8-times more active than the Pd foil, which is astonishing.
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Model Catalysis with HOPG-Supported Pd Nanoparticles and Pd Foil: XPS, STM and C<sub>2</sub>H<sub>4</sub> Hydrogenation.
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