Further, for both reactions in Scheme 1 , the catalytic activity of the machinery shows a clear trend along DS3⋅ NMP> DS3′⋅ NMP> DS3′′⋅ NMP suggesting that the faster motion of both bipeds in DS3 is relevant for the higher turnover (see Supporting Information, Figures S65 and S66).
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Synchronizing Two Distinct Nano-Circular Sliding Motions in Six-Component Machinery for Double Catalysis.
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