The WBI calculated between the U and Ir centers for 1 is 0.97, suggesting a high degree of covalency in the U–Ir interaction, and although the WBI found between Th and Ir in 2 is lower at 0.65, it is still quite significant and strongly implies a metal–metal bonding interaction.
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A versatile strategy for the formation of hydride-bridged actinide-iridium multimetallics.
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