Although the Co–N–C angles are slightly bent, they do not show a clear trend or difference between the Co II and Co III ions.
← all excerpts
K⊂{[Fe<sup>II</sup>(Tp)(CN)<sub>3</sub>]<sub>4</sub>[Co<sup>III</sup>(<sup>pz</sup>Tp)]<sub>3</sub>[Co<sup>II</sup>(<sup>pz</sup>Tp)]}: a neutral soluble model complex of photomagnetic Prussian blue analogues.
2
—
—
The sentences
Despite our efforts to synthesise better-ordered crystal phases, the structural disorder seems to be a marked trend in these cubic systems.